Angew. Chem. Int. Ed. 27. October 2017

http://DOI: 10.1002/anie.201709685

Mathias Flinker, Hongfei Yin, René W. Juhl, Espen Z. Eikeland, Jacob Overgaard, Dennis U. Nielsen* and Troels Skrydstrup*

 

A series of crystalline sp3-sp3 diboron(4) compounds were synthesized and shown to promote the facile reduction of water with dihydrogen formation. The application of these diborons as simple and effective dihydrogen and dideuterium sources was demonstrated by conducting a series of selective reductions of alkynes and alkenes and hydrogen-deuterium exchange reactions with two-chamber reactors. Finally, as the water reduction reaction generates an intermediate borohydride species, a range of aldehydes and ketones could be reduced with water as the hydride source.